Azula
Avatar: The Last Airbender · 2005
A fourteen-year-old prodigy who was raised as a weapon
A top student with a notebook and a god complex
Editorial estimates on a 0–100 scale, calibrated against every other character in the index. Not official canon.
Light finds a supernatural notebook that kills anyone whose name is written in it, and within days he has decided to remake the world as its judge. The series is almost entirely a battle of deduction between him and a detective, with no action at all, and it works because Light is genuinely brilliant and genuinely monstrous, often within the same scene.
He can kill anyone whose face and name he knows, from anywhere, without leaving evidence.
Arrogance. He cannot resist proving he is the smartest person in the room.
The series is almost entirely deduction, and he wins most of the exchanges. His mistakes come from arrogance, never from reasoning.
A gifted student handed unlimited power at eighteen. The story is careful to show that he was not a monster before he found the notebook.
A series with almost no action that stays gripping for forty episodes because the villain is smarter than everyone and losing anyway.